Search results for "Square wave"
showing 10 items of 16 documents
PD characteristics at Square Shaped Voltages Applying Two Different Detecting Techniques
2016
Nowadays power electronic converters are widely used and the fast switching voltage fronts results in an increased stress on the insulation material and may cause a reduction of the HV systems reliability. Nonsinusoidal voltage waveform have influence on the partial discharges (PD) characteristics in insulating systems due to the increased harmonic content which causes problems mainly in electrical PD measurement setups. In fact, impulse voltages cause strong switching disturbances, which make it much more difficult to distinguish PD signals from noise. This work investigates the influence of repetitive steep pulses on different types of test objects exposed to square wave voltages applying…
Study of Redox Processes in Zeolite Y-Associated 2,4,6-Triphenylthiopyrylium Ion by Square Wave Voltammetry
2003
The electrochemical responses of 2,4,6-triphenylthiopyrylium ion (TTP+) in solution and attached to zeolite Y (TTP@Y) are described using cyclic and square wave voltammetries upon immersion of zeolite-modified polymer film electrodes in MeCN (LiClO4, Et4NClO4, and BuN4PF6 electrolytes) and aqueous (LiNO3, NaNO3, and KNO3 electrolytes) media. The electrochemistry of TTP@Y in contact with Bu4NPF6/MeCN is identical to that of TTP(BF4) in solution, with reduction processes at −0.25, −0.74, and −1.36 V vs SCE, and oxidation steps at +0.85 and +1.11 V. This response differs from those obtained for TTP@Y in Et4NClO4/MeCN and LiClO4/MeCN electrolytes. In contact with aqueous electrolytes, TTP@Y dis…
Electrochemistry of copper complexes with macrocyclic polyamines containing pyrazole units.
2006
The voltammetric behaviour of bi- and mono-nuclear complexes formed in solution by Cu(2+) with three polyazacyclophanes containing pyrazole units in aqueous solution is described. Cyclic and square wave voltammetric responses at glassy carbon electrodes indicate that the reduction of copper-macrocycle complexes in solution takes place in two successive one-electron per Cu transfer processes coupled with preorganization and protonation reactions that mimic the behaviour of superoxide dismutase. The electrochemistry of ternary Cu(2+)-receptor-dopamine complexes exhibits significant differences with respect to the protection of the neurotransmitter from post-electron transfer cyclization react…
Square wave voltammetric determination of the redox state of a reversibly oxidized/reduced depolarizer in solution and in solid state
2012
Abstract Square wave voltammetric measurements allows for determining the composition of system containing a reversibly reducible/oxidable electroactive species in two oxidation states. The method is based on recording the ratio of reverse to forward peak currents. That ratio can be correlated with the molar fraction of the oxidized (or reduced) form of the depolarizer. The method was compared with cyclic voltammetric methods suggested in literature and it was tested using Fe ( CN ) 6 3 - / Fe ( CN ) 6 4 - in solution phase. Application to solid state systems is illustrated by the dehydroindigo/indigo couple in synthetic Maya Blue-type specimens prepared from indigo plus different clays whe…
Thermal NDE of thick GRP panels by means of a Pulse Modulated Lock-In Thermography technique
2010
This work describes the development and implementation of an infrared thermal NDE procedure for the evaluation of subsurface defects. The approach is called Pulse-Modulated Lock-In Thermography (PMLT) and is based on the analysis of the frequency response of the measured temperature and comparison with the carrier frequencies launched by the external heat delivering source. The heat deposited on the object is in particular modulated as a train of square waves. This is easily achieved by periodically shuttering the heat source. The temperature is then sampled throughout the deposition of a few square waves. A lock-in algorithm is then implemented able to selectively filter out components at …
Electrochemical Characterization of Archaeological Tin-Opacified Lead-Alkali Glazes and Their Corrosion Processes
2005
The electrochemical response of weathered and unweathered archaeological tin-opacified glazes attached to paraffin-impregnated graphite electrodes is described. Upon comparison with the square wave voltammetric response of SnO2, PbO and PbO2, Sn- and Pb-centered reduction processes can be characterized. Reduction of Sn(IV) involves the stepwise formation of solid Sn(II) and Sn metal, successively, at potentials of −0.08 and −0.55 V vs. AgCl/Ag. Reduction of network-modifier Pb(II) in glazes occurs at −0.5 V and is accompanied by the reduction of network-forming Pb(IV) at potentials ranging from +0.65 to +0.20 V, confirming the presence of such centers in glazes. Voltammetric data suggest th…
Reagent free electrochemical-based detection of silver ions at interdigitated microelectrodes using in-situ pH control
2021
Abstract Herein we report on the development of an electrochemical sensor for silver ions detection in tap water using anodic sweep voltammetry with in-situ pH control; enabled by closely spaced interdigitated electrode arrays. The in-situ pH control approach allowed the pH of a test solution to be tailored to pH 3 (experimentally determined as the optimal pH) by applying 1.65 V to a protonator electrode with the subsequent production of protons, arising from water electrolysis, dropping the local pH value. Using this approach, an initial proof-of-concept study for silver detection in sodium acetate was undertaken where 1.25 V was applied during deposition (to compensate for oxygen producti…
A simulation and experimental study of electrochemical pH control at gold interdigitated electrode arrays
2021
Abstract In electroanalysis, solution pH is a critical parameter that often needs to be tailored and controlled for the detection of particular analytes. This is most commonly performed by the addition of chemicals, such as strong acids or bases. Electrochemical in-situ pH control offers the possibility for the local adjustment of pH at the point of detection, without the need for additional reagents. Finite element analysis (FEA) simulations have been performed on interdigitated electrodes, to guide experimental design in relation to both electroanalysis and in-situ control of solution pH. No previous model exists that describes the generation of protons at an interdigitated electrode arra…
Colloidal crystal motion in electric fields
2003
Abstract We report on the short and long time flow behaviour of colloidal crystals subjected to a homogeneous electrical square wave a.c.-field in closed cells of rectangular cross section. Local velocities are determined from Laser Doppler velocimetry, sample structure and morphology were observed by time resolved polarisation microscopy. We observe a complex time dependence of the flow behaviour. After each field reversal we find a transition from an initial parabola-like flow to a final plug-like flow. On the time scale of minutes to hours channel narrowing occurs, i.e. flow initially restricted by the cell walls becomes restricted to the cell centre by wall based stationary crystals. Wi…
Red-green flicker resolution as a function of heterochromatic luminous modulation.
1993
Critical fusion frequencies have been evaluated in heterochromatic red-green flicker as a function of red-green luminous modulation defined by mL = (R-G)/(R+G)%, at five different mean luminance levels, two test sizes (2 degrees and 5 degrees) and square wave stimuli. The extreme values mL = +/- 100 correspond to ordinary light-dark flicker (red or green); mL = 0 corresponds to pure chromatic flicker, and any other values correspond to simultaneous luminous and chromatic flicker. To implement the stimuli we have developed a new stimuli generator (AVICO, colour vision analyser) using bicolour LEDs as the light source and electronic control of the luminances and frequencies. The results for a…